Author/Authors :
Gao، نويسنده , , Guang and Bai، نويسنده , , Xing-Feng and Li، نويسنده , , Fei and Zheng، نويسنده , , Long-Sheng and Zheng، نويسنده , , Zhan-Jiang and Lai، نويسنده , , Guo-Qiao and Jiang، نويسنده , , Kezhi and Li، نويسنده , , Fuwei and Xu، نويسنده , , Li-Wen، نويسنده ,
Abstract :
We report here the first example of the reduction of acylsilanes to α-hydroxysilanes, in which diethylzinc was used as a highly reactive agent in the presence of Ti(OiPr)4 or other Lewis acids. The reduction typically proceeds to give synthetically useful α-hydroxysilanes in good yields.
Keywords :
Organosilicon chemistry , Reduction , Diethylzinc , Lewis acid , silane
