Title of article :
Stereoselective propargylation of glycals with allenyltributyltin(IV) via a Ferrier type reaction
Author/Authors :
Drew، نويسنده , , Mark D. and Wall، نويسنده , , Mark C. and Kim، نويسنده , , Joseph T.، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2012
Abstract :
Stereoselective introduction of an unsubstituted propargyl group to various glycals was achieved using a Ferrier type reaction with allenyltributyltin(IV). The stereoselectivity was observed based on the conformational preference of glycals as well as steric control of rigid bicyclic systems.
Keywords :
Propargylation , C-Glycosides , Allenyltributyltin , Ferrier reaction , Vinylogous anomeric effect
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
