Title of article
Photoreduction of zinc 3-acetyl-chlorophyll derivative to prepare chemically stable isobacteriochlorin
Author/Authors
Tamiaki، نويسنده , , Hitoshi and Xu، نويسنده , , Meiyun and Mizoguchi، نويسنده , , Tadashi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2012
Pages
3
From page
3210
To page
3212
Abstract
Photochemical reaction of zinc 3-acetyl-chlorophyll derivative possessing a chlorin π-system (trans-17,18-dihydroporphyrin) in the presence of a reductant in a deaerated solution gave trans-2,3-dihydrogenated products in 94% yield based on consumed starting material. The resulting photoreduced products are chemically stable and provide useful samples for investigation of isobacteriochlorins, 2,3,17,18-tetrahydroporphyrinoids.
Keywords
Hydrogenation , Chlorophyll , Isobacteriochlorophyll , Photochemical reaction , Stereochemistry
Journal title
Tetrahedron Letters
Serial Year
2012
Journal title
Tetrahedron Letters
Record number
1881006
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