Title of article :
First total synthesis of (+)-heteroplexisolide E
Author/Authors :
Kutsumura، نويسنده , , Noriki and Kiriseko، نويسنده , , Akito and Saito، نويسنده , , Takao، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2012
Abstract :
In this study, we achieved the first total synthesis of (+)-heteroplexisolide E. The synthetic highlights of our approach include a one-pot regioselective methylation method and the transformation of a β-methallyl alcohol moiety to a prenyl group using palladium-catalyzed hydrogenolysis.
Keywords :
Aldol condensation , Palladium-catalyzed hydrogenolysis , Heteroplexisolide E , One-pot regioselective methylation , total synthesis
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
