Title of article :
The first selective one-pot synthesis of 1,3-dicarbonyl adamantanes from adamantane and 1,3-dimethyladamantane
Author/Authors :
Akhrem، نويسنده , , Irena S. and Avetisyan، نويسنده , , Dzhul’etta V. and Afanas’eva، نويسنده , , Luidmila V.، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2012
Abstract :
A new approach to a simple one-pot functionalization of adamantane and 1,3-dimethyladamantane with CO and various nucleophiles in the presence of the superelectrophilic complex, CBr4·2AlBr3 provides access to important 1,3-dicarbonyl adamantanes with two new functional groups at the bridge-head positions.
Keywords :
one-pot synthesis , sp3 C–H bifunctionalization of adamantanes , 3-Dicarbonyl adamantanes , Superelectrophiles , 1
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
