Title of article
The first selective one-pot synthesis of 1,3-dicarbonyl adamantanes from adamantane and 1,3-dimethyladamantane
Author/Authors
Akhrem، نويسنده , , Irena S. and Avetisyan، نويسنده , , Dzhul’etta V. and Afanas’eva، نويسنده , , Luidmila V.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2012
Pages
4
From page
3493
To page
3496
Abstract
A new approach to a simple one-pot functionalization of adamantane and 1,3-dimethyladamantane with CO and various nucleophiles in the presence of the superelectrophilic complex, CBr4·2AlBr3 provides access to important 1,3-dicarbonyl adamantanes with two new functional groups at the bridge-head positions.
Keywords
one-pot synthesis , sp3 C–H bifunctionalization of adamantanes , 3-Dicarbonyl adamantanes , Superelectrophiles , 1
Journal title
Tetrahedron Letters
Serial Year
2012
Journal title
Tetrahedron Letters
Record number
1881121
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