Author/Authors :
Thakur، نويسنده , , Pallavi and Kumaraswamy، نويسنده , , B. and Raji Reddy، نويسنده , , G. and Bandichhor، نويسنده , , Rakeshwar and Mukkanti، نويسنده , , K.، نويسنده ,
Abstract :
The first stereoselective total synthesis of polyacetylene panaxjapyne C is described. The key reactions include regioselective opening of the epoxide and Cadiot–Chodkiewicz cross-coupling reactions. l-Ascorbic acid was used as a chiral pool material for the construction of the both terminal acetylenes.
Keywords :
Polyacetylene , Regioselective opening of epoxide , Cadiot–Chodkiewicz cross coupling , l-Ascorbic acid , Araliaceae