Title of article
Deoxygenation/dimerization of sugar derivatives with BF3·Et2O–Et3SiH: synthesis of a β-isonucleoside
Author/Authors
Mukherjee، نويسنده , , Subhrangshu and Roy، نويسنده , , Biswajit G. and Das، نويسنده , , Soumendra N. and Mandal، نويسنده , , Sukhendu B.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2012
Pages
4
From page
4929
To page
4932
Abstract
Lewis acid-Et3SiH induced deoxygenation of anomeric carbon of sugars generates tetrahydrofuran derivatives, accompanied by hitherto unknown dimeric products. If the reagent addition steps are reversed, tetrahydrofuran derivatives are obtained as the sole products, while only the dimeric products are isolated if Et3SiH is excluded. One of the deoxygenated products has been transformed into a β-isonucleoside.
Keywords
triethylsilane , Boron trifluoride-etherate , deoxygenation , dimerization , Synthesis , Isonucleosides
Journal title
Tetrahedron Letters
Serial Year
2012
Journal title
Tetrahedron Letters
Record number
1881757
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