Title of article
Ireland–Claisen rearrangement of ynamides: stereocontrolled synthesis of 2-amidodienes
Author/Authors
Heffernan، نويسنده , , Stephen J. and Carbery، نويسنده , , David R.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2012
Pages
3
From page
5180
To page
5182
Abstract
The Ireland–Claisen rearrangement of propargyl ynamido ester substrates is reported. The expected allenamide carboxylic acid products from [3,3]-sigmatropic rearrangement are not isolated, with 2-amidodienes alternatively formed in good yield with high levels of stereocontrol after decarboxylation.
Keywords
Sigmatropic , Ireland–Claisen , Furanomycin , Amino acid , Rearrangement
Journal title
Tetrahedron Letters
Serial Year
2012
Journal title
Tetrahedron Letters
Record number
1882023
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