Title of article
Synthesis of N1,N3-disubstituted formamidrazones via the TMSCl-promoted reaction of isocyanides with thiosemicarbazones
Author/Authors
Pakornwit Sarnpitak، نويسنده , , Pakornwit and Tsirulnikov، نويسنده , , Sergey and Krasavin، نويسنده , , Mikhail، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2012
Pages
4
From page
6540
To page
6543
Abstract
A hitherto undescribed TMSCl-promoted reaction of thiosemicarbazones was found to give rare N1,N3-disubstituted formamidrazones in fair to excellent yields. The scope of this new reaction was investigated and a plausible mechanism proposed.
Keywords
Formamidrazones , Lewis acid catalysis , Isocyanide-based multicomponent reactions , Isocyanide insertion , chlorotrimethylsilane
Journal title
Tetrahedron Letters
Serial Year
2012
Journal title
Tetrahedron Letters
Record number
1882812
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