Title of article :
Cinchona alkaloids induce asymmetry in the insertion reaction of thermally generated carbenes into N−H bonds
Author/Authors :
Saito، نويسنده , , Hiroaki and Morita، نويسنده , , Daisuke and Uchiyama، نويسنده , , Taketo and Miyake، نويسنده , , Muneharu and Miyairi، نويسنده , , Shinichi، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2012
Pages :
3
From page :
6662
To page :
6664
Abstract :
Ammonium ylides generated in situ from phenyldiazoacetates and anilines undergo asymmetric N−H insertion reactions catalyzed by cinchona alkaloids (1 mol %), affording phenylglycines up to 74% ee.
Keywords :
asymmetric synthesis , Carbene , N?H insertion reaction , organocatalysis , Thermolysis
Journal title :
Tetrahedron Letters
Serial Year :
2012
Journal title :
Tetrahedron Letters
Record number :
1882858
Link To Document :
https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1882858
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