Title of article :
Radical 1,4-phenyl migration favored by C−H⋯O interaction. A theoretical investigation
Author/Authors :
Sandoval-Lira، نويسنده , , Jacinto and Hernلndez-Pérez، نويسنده , , Julio M. and Sartillo-Piscil، نويسنده , , Fernando، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2012
Abstract :
Theoretical calculations provided strong evidences supporting the existence of C−H⋯O interactions that determine the rotamer equilibrium of chiral amide radicals derived from α-methylbenzylamine and, therefore, favors the radical 1,4-phenyl migration reaction.
Keywords :
Amides , radicals , C?H?O interaction , Migration , rotamers
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
