Title of article
Sc(OTf)3-catalyzed synthesis of thiosulfonates in ionic liquid-water
Author/Authors
Liang، نويسنده , , Gaigai and Chen، نويسنده , , Jing and Chen، نويسنده , , Jiali and Li، نويسنده , , Wanmei and Chen، نويسنده , , Jiuxi and Wu، نويسنده , , Huayue، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2012
Pages
3
From page
6768
To page
6770
Abstract
The first example of Sc(OTf)3-catalyzed sulfenylation of sodium sulfinates with N-(organothio)succinimides in ionic liquids (ILs) and water cosolvent system was developed, achieving thiosulfonates in moderate to excellent yields. Additionally, Sc(OTf)3/ILs could be recovered easily after the reactions and reused without a significant loss in the catalytic activity. Thus, the present protocol represents an interesting complement to known methods for thiosulfonates synthesis.
Keywords
Sc(OTf)3 , Ionic liquid , N-(Organothio)succinimide , thiosulfonates , sulfinate
Journal title
Tetrahedron Letters
Serial Year
2012
Journal title
Tetrahedron Letters
Record number
1882917
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