Title of article :
Enantioselective iridium-catalyzed allylation of sodium benzotriazolide: an efficient way to chiral allylbenzotriazoles
Author/Authors :
Zhang، نويسنده , , Min and Guo، نويسنده , , Xin-Wen and Zheng، نويسنده , , Sheng-Cai and Zhao، نويسنده , , Xiao-Ming، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2012
Abstract :
A highly enantioselective allylic substitution of sodium benzotriazolide has been attained in the presence of [Ir(COD)Cl]2/phosphoramidite ligand L1 together with K3PO4 as an additive, producing enantioenriched allylbenzotriazole compounds with up to 98% ee.
Keywords :
Sodium benzotriazolide , iridium , Asymmetric allylation , Phosphoramidite ligand
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
