Title of article
An efficient oxidative coupling method for synthesis of novel diastereomeric biaryl diols derived from estrone
Author/Authors
Feng، نويسنده , , Jie and Yang، نويسنده , , Xin-Bin and Liang، نويسنده , , Shuai and Zhang، نويسنده , , Ji and Yu، نويسنده , , Xiao-Qi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2013
Pages
3
From page
355
To page
357
Abstract
An efficient oxidative coupling of estrogen derivatives was developed. Several 2-substitutent-17-deoxyestrones were applied to the aerobic oxidative coupling reactions catalyzed by CuCl2/TMEDA. The products were obtained as diastereoisomers with moderate to good yields. As chiral ligands, three couples of diastereoisomers were applied to the asymmetric HDA reaction to investigate their chemical properties.
Keywords
oxidative coupling , Estrogen derivatives , Substituent , Diastereoisomers
Journal title
Tetrahedron Letters
Serial Year
2013
Journal title
Tetrahedron Letters
Record number
1883491
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