Title of article :
In situ generation of hydroperoxide by oxidation of benzhydrols to benzophenones using sodium hydride under oxygen atmosphere: use for the oxidative cleavage of cyclic 1,2-diketones to dicarboxylic acids
Author/Authors :
Kang، نويسنده , , Sunhae and Lee، نويسنده , , Soyoung and Jeon، نويسنده , , Minju and Kim، نويسنده , , Sun Min and Kim، نويسنده , , Young Sug and Han، نويسنده , , Hogyu and Yang، نويسنده , , Jung Woon، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2013
Abstract :
A facile oxidative cleavage of cyclic 1,2-diketones 1 to dicarboxylic acids 3 with hydroperoxide generated in situ has been developed. In situ generation of hydroperoxide was effected by the oxidation of 4,4′-dichlorobenzhydrol 2f to 4,4′-dichlorobenzophenone 4f using sodium hydride under oxygen atmosphere.
Keywords :
Sodium hydride , Benzhydrol , Cyclic 1 , 2-Diketone , Oxidative cleavage , Dicarboxylic acid
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
