Title of article :
Enantioselective total synthesis of (−)-ericanone
Author/Authors :
Dias، نويسنده , , Luiz C. and Kuroishi، نويسنده , , Paula K. and Polo، نويسنده , , Ellen C. and de Lucca Jr.، نويسنده , , Emيlio C.، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2013
Abstract :
The first total synthesis of (−)-ericanone was achieved in 10 steps with a 16% overall yield from p-hydroxybenzaldehyde. Notable features of this stereocontrolled approach include a Keck allylation to install the stereocenter at C3 and a 1,5-anti aldol reaction to install the hydroxyl group at C7.
Keywords :
total synthesis , natural product , (?)-Ericanone , aldol reaction , Boron enolate
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
