Title of article :
Grignard allylic substitution reaction catalyzed by 1,2,3-triazol-5-ylidene magnesium complexes
Author/Authors :
Nomura، نويسنده , , Ryosuke and Tsuchiya، نويسنده , , Yuji and Ishikawa، نويسنده , , Hiroyuki and Okamoto، نويسنده , , Sentaro، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2013
Abstract :
Allylic chlorides and phosphates reacted with alkyl-Grignard reagent in an SN2′-selective manner in the presence of a catalytic amount of 1,2,3-triazol-5-ylidenes to provide α-branched alkenes.
Keywords :
12 , 3-Triazol-5-ylidene , SN2?-selective , allylic substitution , Grignard reagent
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
