Title of article
Intramolecular reductive cyclization of an enone–aldehyde: a new approach to the synthesis of (±)-majusculone
Author/Authors
Hsu، نويسنده , , Day-Shin and Juo، نويسنده , , Bing-Chiuan، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2013
Pages
3
From page
1751
To page
1753
Abstract
A concise total synthesis of (±)-majusculone from 2,6,6-trimethyl-2-cyclohexen-1-one in seven steps is described. Intramolecular reductive cyclization of an enone–aldehyde using samarium diiodide is the key step in this synthesis.
Keywords
reductive cyclization , Samarium diiodide , total synthesis , Chamigrene , Majusculone
Journal title
Tetrahedron Letters
Serial Year
2013
Journal title
Tetrahedron Letters
Record number
1884116
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