Title of article
Selective reduction of dienes/polyenes using sodium borohydride/catalytic ruthenium(III) in various liquid amide aqueous mixtures
Author/Authors
Babler، نويسنده , , James H. and Ziemke، نويسنده , , David W. and Hamer، نويسنده , , Robert M.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2013
Pages
4
From page
1754
To page
1757
Abstract
An efficient method to effect selective reduction of several structurally diverse dienes and an unsymmetrical triene is reported. The reduction is facile at 0 °C in a liquid amide aqueous solution containing sodium borohydride in the presence of 15 mol % ruthenium(III) chloride. The chemoselectivity of the reaction is controlled by proper choice of the liquid amide solvent.
Keywords
ruthenium trichloride , Liquid carboxamides , sodium borohydride , Selective reduction of dienes
Journal title
Tetrahedron Letters
Serial Year
2013
Journal title
Tetrahedron Letters
Record number
1884117
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