Title of article :
RCM strategy-based entry into new crown ether/polyether macrocyclic systems derived from hydroxy benzaldehydes
Author/Authors :
Naveen and Parella، نويسنده , , Ramarao and Babu، نويسنده , , Srinivasarao Arulananda، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2013
Abstract :
Entry into the 16–24 membered new crown ether/polyether macrocyclic molecules and the post ring-closure functional derivatization/periphery modification of polyether macrocyclic systems are reported. The synthesis of the epoxide, α-hydroxy ketone and olefinic functionality installed crown ether/polyether macrocyclic molecules was accomplished using the ring closing metathesis (RCM), epoxidation, oxidation and catalytic hydrogenation-based synthetic transformations starting from various hydroxy benzaldehydes.
Keywords :
Epoxide functionality , Grubbs’s catalyst , Macrocycles , Ring closing metathesis , Hydroxy ketone functionality , Crown Ethers
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters