Title of article
CaF2 catalyzed SN2 type chlorodehydroxylation of chiral secondary alcohols with thionyl chloride: a practical and convenient approach for the preparation of optically active chloroalkanes
Author/Authors
Zhang، نويسنده , , Junjie and Wang، نويسنده , , Huanxia and Ma، نويسنده , , Yun and Wang، نويسنده , , Youming and Zhou، نويسنده , , Zhenghong and Tang، نويسنده , , Chuchi Tang، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2013
Pages
3
From page
2261
To page
2263
Abstract
A CaF2 catalyzed chlorodehydroxylation of chiral secondary alcohols with thionyl chloride has been developed. The chlorination reaction is effective for a wide range of alcohols, generating the corresponding chloroalkanes in good yield with high optical purity with inversion of the original configuration of the alcohol.
Journal title
Tetrahedron Letters
Serial Year
2013
Journal title
Tetrahedron Letters
Record number
1884306
Link To Document