Author/Authors :
Nageshwar R. Yepuri، نويسنده , , Nageshwar R. and Jamieson، نويسنده , , Scott A. and Darwish، نويسنده , , Tamim A. and Rawal، نويسنده , , Aditya and Hook، نويسنده , , James M. and Thordarson، نويسنده , , Pall and Holden، نويسنده , , Peter J. and James، نويسنده , , Michael، نويسنده ,
Abstract :
A general, direct and scalable synthesis of per-deuterated alkyl amines is reported, together with their incorporation into pyromellitamides, which form self-assembled gels in cyclohexane. The deuterium labelling of these gelators allows the study of the dynamic intermolecular interactions in these materials using solid-state 2H NMR spectroscopy.
Keywords :
Self-assembling organogels , Deuterated amines , Supramolecular chemistry , Solid state deuterium NMR