Author/Authors :
Gonçalves، نويسنده , , Lَren C.C. and Lima، نويسنده , , David B. and Borba، نويسنده , , Pedro M.Y. and Perin، نويسنده , , Gelson and Alves، نويسنده , , Diego and Jacob، نويسنده , , Raquel G. and Lenardمo، نويسنده , , Eder J.، نويسنده ,
Abstract :
A convenient approach to the Cu-catalyzed coupling of diphenyl disulfide and diphenyl ditelluride with vinyl bromides using a recyclable catalytic system and glycerol as a green solvent is described. This protocol was efficiently used in the preparation of vinyl sulfides and vinyl tellurides with a variety of substituents in good yields and stereoselectively. The solvent/catalyst system was directly reused for four cycles without loss of activity.
Keywords :
cross-coupling , Glycerol , Vinyl sulfides , Vinyl tellurides