Title of article :
Unexpected opening of steroidal E-ring during hypoiodite-mediated oxidation
Author/Authors :
Kou، نويسنده , , Yi and Lee، نويسنده , , Seongmin، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2013
Abstract :
In this Letter, we report unexpected formation of E-ring opened steroidal alkaloid from primary amine presumably via a hypoiodite-mediated iodoamination followed by fragmentation of sterically congested iodospiroaminal.
Keywords :
Hypoiodite , Aminyl radical cyclization , Steroidal alkaloid , Solasodine , Steroidal ring opening
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
