Author/Authors :
Sigwalt، نويسنده , , David and Schillinger، نويسنده , , Franck and Guerra، نويسنده , , Sebastiano and Holler، نويسنده , , Michel and Berville، نويسنده , , Mathilde and Nierengarten، نويسنده , , Jean-François، نويسنده ,
Abstract :
A threefold Bingel reaction between C60 and t-butyl(trialkoxy)silane derivatives bearing three malonate substituents gave access to fullerene e,e,e tris adducts. Subsequent desilylation with HF·pyridine or BF3·Et2O afforded the corresponding fullerene tris-adducts bearing three alcohol functions.
Keywords :
regioselectivity , Trialkoxysilane , Fullerene , Malonates