Title of article :
Synthesis of unsymmetrical polyfluorinated diaryl sulfides by rhodium-catalyzed aryl exchange reaction
Author/Authors :
Arisawa، نويسنده , , Mieko and Ichikawa، نويسنده , , Takuya and Yamaguchi، نويسنده , , Masahiko، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2013
Abstract :
RhH(PPh3)4 and 1,2-bis(diphenylphosphino)benzene (dppBz) catalyze the aryl exchange reaction of polyfluorinated diaryl sulfides. By employing these catalysts, unsymmetrical polyfluorinated diaryl sulfides are synthesized by the reaction of symmetrical polyfluorinated diaryl sulfides and substituted pentafluorobenzenes in the presence of triisopropylsilane.
Keywords :
Unsymmetrical polyfluorinated diaryl sulfides , Aryl exchange reaction , Symmetrical polyfluorinated diaryl sulfides , Rhodium catalyst , Pentafluorobenzenes
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
