Title of article
Synthesis and spectroscopic properties of 5-tert-butyl-3-(trifluoromethyl)phthalonitrile: a novel precursor for the synthesis of phthalocyanines
Author/Authors
?apok، نويسنده , , ?ukasz and Gut، نويسنده , , Arkadiusz and Nowakowska، نويسنده , , Maria، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2013
Pages
4
From page
4388
To page
4391
Abstract
The synthesis and spectroscopic characterization of the new phthalonitrile 5-tert-butyl-3-(trifluoromethyl)phthalonitrile is reported. A six-step route, which started with a regiospecific iodination, followed by CuI-catalyzed trifluoromethylation, is discussed. The title compound is also converted into the more reactive compound 6-tert-butyl-4-trifluoromethyl-1,3-diiminoisoindoline.
Keywords
phthalonitriles , Electrophilic Substitution , Phthalocyanines , Nucleophilic trifluoromethylation
Journal title
Tetrahedron Letters
Serial Year
2013
Journal title
Tetrahedron Letters
Record number
1885205
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