Title of article
Direct conversion of glycerol into formic acid via water stable Pd(II) catalyzed oxidative carbon–carbon bond cleavage
Author/Authors
Pullanikat، نويسنده , , Prasanna and Lee، نويسنده , , Joo Ho and Yoo، نويسنده , , Kyung Soo and Jung، نويسنده , , Kyung Woon، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2013
Pages
4
From page
4463
To page
4466
Abstract
Using our tridentate NHC-amidate–alkoxide Pd(II) complex, we developed a catalytic method for oxidative C–C bond cleavage of glycerol. The glycerol was degraded exclusively to formic acid and CO2. Two possible degradation pathways were proposed through 13C labeled studies.
Keywords
Degradation of glycerol , Formic acid , Oxidative catalysis , NHC amidate ligand , palladium catalyst
Journal title
Tetrahedron Letters
Serial Year
2013
Journal title
Tetrahedron Letters
Record number
1885235
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