Title of article :
A stereoselective method for the construction of the C8′–O–C6″ ether of nigricanoside-A: synthesis of simple models for the C20 lipid chain/galactosyl glycerol segment
Author/Authors :
Kinashi، نويسنده , , Naoto and Fujiwara، نويسنده , , Kenshu and Tsunoda، نويسنده , , Takayuki and Katoono، نويسنده , , Ryo and Kawai، نويسنده , , Hidetoshi and Suzuki، نويسنده , , Takanori، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2013
Abstract :
A method for the stereoselective construction of the C8′–O–C6″ ether of nigricanoside-A, an antimitotic natural product from the green alga Avrainvillea nigricans, has been developed based on chirality-transferring Ireland–Claisen rearrangement. The method was successfully applied to the synthesis of simple models for the C20 lipid chain/galactosyl glycerol segment of the natural product.
Keywords :
natural product synthesis , Monogalactosyl diacyl glycerol , Ireland–Claisen rearrangement , Ether lipid , stereoselective synthesis
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
