Author/Authors :
Reddy، نويسنده , , B.V. Subba and Reddy، نويسنده , , P. Sivaramakrishna and Reddy، نويسنده , , B. Phaneendra and Yadav، نويسنده , , J.S. and Al Khazim Al Ghamdi، نويسنده , , Ahamad، نويسنده ,
Abstract :
A stereoselective total synthesis of xyolide is described employing MacMillan α-hydroxylation, Steglich esterification, and ring closing metathesis as key steps. The use of organocatalytic MacMillan α-hydroxylation to construct two of the chiral centers of the xyolide makes this approach attractive.
Keywords :
Steglich esterification , Ring closing metathesis , Xyolide , MacMillan aminooxylation
