Author/Authors :
Mahmood، نويسنده , , Mian HR and Liu، نويسنده , , Hai-Yang and Wang، نويسنده , , Hua-Hua and Jiang، نويسنده , , Yi-Yu and Chang، نويسنده , , C.-K.، نويسنده ,
Abstract :
The first direct synthesis of A3-type unsymmetrical porphyrin is achieved via conventional pyrrole–aldehyde condensation in a one-pot procedure in an appreciable yield. Generalization of this approach to a variety of other aldehydes revealed that it is advantageous for highly electron-rich aldehydes giving unsymmetrical porphyrin, while electron-poor aldehydes even failed to cyclize under the same experimental conditions.
Keywords :
Unsymmetrical porphyrin , corrole , Pyrrole–aldehyde condensation , Synthesis
