Author/Authors :
Schaefer، نويسنده , , Sara L. and Roberts، نويسنده , , Connor L. and Volz، نويسنده , , Erasmus O. and Grasso، نويسنده , , Monika R. and O’Neil، نويسنده , , Gregory W.، نويسنده ,
Abstract :
Aromatic allylic benzoates can be selectively transformed to the corresponding benzoate eliminated olefin by the action of samarium diiodide. Depending on the substrate and the elimination conditions, high selectivity for the non-conjugated alkene product can be achieved.
Keywords :
elimination , Non-conjugated , Isomerization , Samarium
