Author/Authors :
Rong، نويسنده , , Bin and Ding، نويسنده , , Lei and Yu، نويسنده , , Hailei and Yang، نويسنده , , Qin and Liu، نويسنده , , Xuliang and Xu، نويسنده , , Dongfang and Li، نويسنده , , Guisheng and Zhao، نويسنده , , Baoguo، نويسنده ,
Abstract :
This work describes the first Pd-catalyzed allylic alkylation of thioamides. Various thioamides were efficiently α-allylated in high yields and with excellent selectivity for monoallylation under mild reaction conditions. The process not only provides a facile method for the synthesis of functionalized thioamides, but also presents a useful transformation for synthetically important thioamides.
Keywords :
allylic alkylation , PALLADIUM , Catalysis , Thioamide , allylation
