Author/Authors :
Vi??ovsk?، نويسنده , , Jozef and Billik، نويسنده , , Peter and Kubinec، نويسنده , , R?bert and Podolec، نويسنده , , Peter and Hengerics Szab?، نويسنده , , Alexandra and Juriga، نويسنده , , Martin and ?abala، نويسنده , , Radom?r and Kubincov?، نويسنده , , Janka and Bla?ko، نويسنده , , Jaroslav، نويسنده ,
Abstract :
Solvent-free chlorination of biphenyl and naphthalene was performed under mechanochemical stressing by high-energy ball milling (HEM) of a mixture of CuCl2 (95 wt %) and the hydrocarbon (5 wt %). The reactivity of the selected hydrocarbons towards CuCl2 during HEM partially correlates with their ionisation potentials (IP): hexadecane (9.91 eV) > biphenyl (8.27 eV) > naphthalene (8.14 eV).
Keywords :
mechanochemistry , high-energy ball milling , Chlorination , Hydrocarbons , CuCl2
