Title of article
Palladium-catalyzed asymmetric 1,6-addition of diphenylphosphine to (4-aryl-1,3-butadienylidene)bis(phosphonates) for the synthesis of chiral phosphines
Author/Authors
Huang، نويسنده , , Jian and Zhao، نويسنده , , Mei-Xin and Duan، نويسنده , , Wei-Liang، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2014
Pages
3
From page
629
To page
631
Abstract
An asymmetric 1,6-addition of diphenylphosphine to (4-aryl-1,3-butadienylidene)bis(phosphonates) catalyzed by a PCP pincer–Pd complex has been developed for the synthesis of chiral allylic phosphines with up to 91% ee under mild conditions.
Keywords
Asymmetric 1 , 6-Addition , Pincer palladium catalyst , Bis(phosphonate)-substituted dienes , Chiral phosphines
Journal title
Tetrahedron Letters
Serial Year
2014
Journal title
Tetrahedron Letters
Record number
1887761
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