Title of article :
Synthesis and properties of novel crown ether-annelated 4′,5′-diaza-9′-(1,3-dithiole-2-ylidene)-fluorenes and their ruthenium(II) complexes
Author/Authors :
Sako، نويسنده , , Katsuya and Kakehi، نويسنده , , Toshiaki and Nakano، نويسنده , , Shota and Oku، نويسنده , , Hiroyuki and Shen، نويسنده , , Xu Feng and Iwanaga، نويسنده , , Tetsuo and Yoshikawa، نويسنده , , Manami and Sugahara، نويسنده , , Kouta and Toyota، نويسنده , , Shinji and Takemura، نويسنده , , Hiroyuki and Shinmyozu، نويسنده , , Teruo and Shiotsuka، نويسنده , , Michito and Tatemitsu، نويسنده , , Hit، نويسنده ,
Abstract :
Two novel redox-active 1,3-dithiole (DT) ring-fused 4,5-diazafluorene ligands with crown ether moieties (L1 and L2) were synthesized and characterized. The crystal structure of L1 was studied. The electrochemical and spectroscopic properties of these new ligands, as well as the corresponding bis(bipyridine)ruthenium(II) complexes [4: Ru L1(bpy)2 and 5: Ru L2(bpy)2], were also been investigated.
Keywords :
Ruthenium complexes , pi-Donor , 1 , 3-Dithiole (half-Tetrathiafulvalene) , 4 , 5-Diazafluorene , Crown ether
