Author/Authors :
Li، نويسنده , , Jiazhu and Zhang، نويسنده , , Peng and Yao، نويسنده , , Nan-Nan and Zhao، نويسنده , , Lili and Wang، نويسنده , , Jin-Jun and Shim، نويسنده , , Young Key، نويسنده ,
Abstract :
A practical and efficient methodology for the formation of C–O bonds on the porphyrin/chlorin periphery was developed. The aroyloxy-substituted porphyrins and chlorins related to chlorophyll-a at the β- and meso-positions, respectively, were conveniently synthesized by the free radical substitution reaction with benzoyl peroxide and its homologs.
Keywords :
Benzoyl peroxide , Chlorin , Porphyrin , Aroyloxylation