Title of article
Synthesis of 1-acetyl-2-silyoxycycloheptane derivatives via highly stereoselective formal [5+2] cycloaddition reaction
Author/Authors
Kudo، نويسنده , , Mami and Kondo، نويسنده , , Fumikatsu and Maekawa، نويسنده , , Hideki and Shimizu، نويسنده , , Tadashi and Miyashita، نويسنده , , Masaaki and Tanino، نويسنده , , Keiji، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2014
Pages
4
From page
1192
To page
1195
Abstract
A stereoselective [5+2] cycloaddition reaction using a new five-carbon unit, that has a dicobalt acetylene complex moiety and an enol silyl ether moiety, was developed. In the presence of a Lewis acid, the five-carbon unit reacted with an enol triisopropylsilyl ether to give a 1-acetyl-2-silyoxycycloheptane derivative, in which the three contiguous substituents on the seven-membered ring arrange cis to each other.
Keywords
Cycloheptane , Dicobalt acetylene complex , Cycloaddition reaction , Enol silyl ether
Journal title
Tetrahedron Letters
Serial Year
2014
Journal title
Tetrahedron Letters
Record number
1888160
Link To Document