Title of article :
Preparation of silyl polyenol ethers by carbonyl olefination of silyl esters
Author/Authors :
Takeda، نويسنده , , Takeshi and Fukada، نويسنده , , Tatsuya and Tsubouchi، نويسنده , , Akira، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2014
Abstract :
Silyl enol ethers were produced by the carbonyl olefination of silyl esters with titanium carbene complexes generated by the desulfurizative titanation of thioacetals. The regioselective preparation of silyl dienol and trienol ethers has been achieved by using unsaturated silyl esters and thioacetals.
Keywords :
Titanium carbene complexes , carbonyl olefination , Polyenes , Silyl enol ethers , silyl esters
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters