Title of article
Ring-opening with one dioxygen molecule in the coupled oxidation of iron tetraarylporphyrins
Author/Authors
Sandell، نويسنده , , Jonas P.L. and Kakeya، نويسنده , , Kazuhisa and Mizutani، نويسنده , , Tadashi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2014
Pages
4
From page
1532
To page
1535
Abstract
A dioxygen molecule was activated on the iron complex of tetraarylporphyrins and both oxygen atoms of the O2 molecule were added to cleave the macrocycle to yield a linear tetrapyrrole intermediate, from which two linear tetrapyrrole products, biladienone and bilindione, are formed, as revealed by isotope labeling experiments with oxygen-18.
Keywords
Chlorophyll , Bilin , Oxidation , Porphyrin
Journal title
Tetrahedron Letters
Serial Year
2014
Journal title
Tetrahedron Letters
Record number
1888310
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