Title of article
Alkylcobyrinate from sucralose and mechanistic aspects of its CoC bond cleavage
Author/Authors
Motwani، نويسنده , , Hitesh V. and Shimakoshi، نويسنده , , Hisashi and Golding، نويسنده , , Bernard T. and Tِrnqvist، نويسنده , , Margareta and Hisaeda، نويسنده , , Yoshio، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2014
Pages
4
From page
2667
To page
2670
Abstract
Reaction of heptamethyl cob(I)yrinate with 1′,6′-dichloro-1′,6′-dideoxy-β-d-fructofuranosyl-4-chloro-4-deoxy-α-d-galactopyranoside (sucralose) gave an alkylcobyrinate, heptamethyl-6′-[α-d-galactopyranoside- 1′-chloro-1′,6′-dideoxy-β-d-fructofuranosyl-4-chloro-4-deoxy]cobyrinate perchlorate, [(Suc)Cob(III)7C1ester]ClO4. Cleavage behavior of CoC bond of the alkylcobyrinate was investigated under various conditions (hν, H+ and reduction) using UV–vis spectroscopy combined with the EPR spin-trapping technique, and by cyclic voltammetry.
Keywords
Alkylcobyrinate , Redox behavior , sucralose , CoC bond cleavage , Dechlorination
Journal title
Tetrahedron Letters
Serial Year
2014
Journal title
Tetrahedron Letters
Record number
1889145
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