Author/Authors :
Nakashima، نويسنده , , Kosuke and Hirashima، نويسنده , , Shin-ichi and Kawada، نويسنده , , Masahiro and Koseki، نويسنده , , Yuji and Tada، نويسنده , , Norihiro and Itoh، نويسنده , , Akichika and Miura، نويسنده , , Tsuyoshi، نويسنده ,
Abstract :
The novel pyrrolidine-diaminomethylenemalononitrile organocatalyst 7 promotes the asymmetric conjugate addition of a carbonyl compound to a nitroalkene to afford the corresponding adduct in high yield with up to 99% ee, under solvent-free conditions.
Keywords :
Michael addition , organocatalyst , solvent-free , Diaminomethylenemalononitrile , Nitroalkene
