Title of article :
Mechanistic studies on the diazo transfer reaction
Author/Authors :
Pandiakumar، نويسنده , , Arun Kumar and Sarma، نويسنده , , Siddhartha P. and Samuelson، نويسنده , , Ashoka G.، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2014
Abstract :
The mechanism of the diazo transfer reaction which converts amines to azides has been studied with labeled amino acids and labeled imidazole-1-sulfonyl azides. Retention of amine nitrogen in the amine, and transfer of the two terminal nitrogen atoms of the imidazole-1-sulfonyl azide to the product, were unambiguously established.
Keywords :
Labeled imidazole-1-sulfonyl azide , Imidazole-1-sulfonyl azide·HCl , Labeled l-valine azide , SNi mechanism , Diazo (–N2) transfer
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
