Author/Authors :
Kao، نويسنده , , Joseph P.Y. and Muralidharan، نويسنده , , Sukumaran and Zavalij، نويسنده , , Peter Y. and Fletcher، نويسنده , , Steven and Xue، نويسنده , , Fengtian and Rosen، نويسنده , , Gerald M.، نويسنده ,
Abstract :
Pyrroloxyls have been reported to exhibit very narrow EPR spectral lines, essential for in vivo imaging. En route to pyrroloxyls, we observed an unexpected Baeyer–Villiger rearrangement, leading to loss of aromaticity and formation of a 4,5-dihydro-1H-ketopyrrole.
Keywords :
Pyrroloxyl , Vilsmeier–Haack , Baeyer–Villiger , pyrrole
