Title of article :
Regioselective nucleophilic ring-opening reaction of chiral epoxyallyl alcohols: a ready access to the pyran core of macrolactin 3
Author/Authors :
Radha Krishna، نويسنده , , Palakodety and Nomula، نويسنده , , Rajesh and Rama Krishna، نويسنده , , Kallaganti V.S. Ramakrishna، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2014
Abstract :
Herein we report the synthetic strategy towards the pyran core of macrolactin 3 via Sharpless epoxidation, titanium(IV) mediated regioselective ring-opening reaction of epoxyallyl alcohol/epoxy alcohol and oxa-Michael addition as the key steps.
Keywords :
Macrolactins , Sharpless epoxidation , Regioselective epoxide ring-opening , Oxa-Michael addition
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters