Title of article :
The nucleophilicity of adamantanylidene: a Hammett study
Author/Authors :
Moss، نويسنده , , Robert A. and Cang، نويسنده , , Hui and Krogh-Jespersen، نويسنده , , Karsten، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2014
Abstract :
In its reactions with a series of styrene substrates, adamantanylidene behaves as a nucleophile, exhibiting a Hammett rho value of +2.0. Computational studies support the nucleophilicity of adamantanylidene in styrene addition reactions.
Keywords :
Carbenes , Computational Studies , Styrenes , Cyclopropanation
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
