Title of article :
Mild propargylic oxidation using a diacetoxyiodobenzene/tert-butyl hydroperoxide protocol
Author/Authors :
Zhao، نويسنده , , Yi Han Ng، نويسنده , , Angela Wan Ting and Yeung، نويسنده , , Ying-Yeung and Corey، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2014
Abstract :
A mild propargylic oxidation of alkynes is reported using a diacetoxyiodobenzene/tert-butyl hydroperoxide (DIB/TBHP) protocol. The reactions proceed smoothly at 0 °C and a number of α,β-unsaturated alkynoic ketones are obtained.
Keywords :
Oxidation , alkyne , hypervalent iodine , Selectivity , Ynone
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
