مرکز منطقه ای اطلاع رساني علوم و فناوري - Imidazolinium salts derived from amino[2.2]paracyclophane compounds: synthesis and hydrolytic ring-opening

Title of article :

Imidazolinium salts derived from amino[2.2]paracyclophane compounds: synthesis and hydrolytic ring-opening

Author/Authors :

Green، نويسنده , , Kerry-Ann and Maragh، نويسنده , , Paul T. and Abdur-Rashid، نويسنده , , Kamaluddin and Lough، نويسنده , , Alan J. and Dasgupta، نويسنده , , Tara P.، نويسنده ,

Issue Information :

هفته نامه با شماره پیاپی سال 2014

Pages :

From page :

5085

To page :

5087

Abstract :

The synthesis of a series of imidazolinium chlorides containing the [2.2]paracyclophane scaffold is described. Attempts to deprotonate the salts with strong bases resulted in hydrolytic ring-opening and yielded N-formylethylenediamine products rather than the intended free carbenes.

Keywords :

N-heterocyclic carbene , Paracyclophane , Hydrolysis , N-Formylethylenediamine

Journal title :

Tetrahedron Letters

Serial Year :

2014

Journal title :

Tetrahedron Letters

Record number :

1890595

Link To Document :

https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1890595