Title of article
Phosphonium salt induced stereoselective allylic rearrangement during chlorination of α-hydroxyallylphosphinates
Author/Authors
Ji، نويسنده , , Si-Yu and Sun، نويسنده , , Yongming and Zhang، نويسنده , , He and Hou، نويسنده , , Qing-Gao and Zhao، نويسنده , , Chang-Qiu، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2014
Pages
3
From page
5742
To page
5744
Abstract
α-Hydroxyallylphosphinates were stereoselectively converted to γ-chloro allylphosphinates when treated with Ph3P and CCl4, via substitution of hydroxyl and migration of double bond. The reaction was promoted by phosphonium cation that acted as Lewis acid.
Keywords
Rearrangement , Chlorination , ?-Chloro allylphosphinate , Phosphonium , Lewis acid
Journal title
Tetrahedron Letters
Serial Year
2014
Journal title
Tetrahedron Letters
Record number
1890904
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