Title of article
Rhodium-catalyzed tandem aldol condensation–Robinson annulation between aldehydes and acetone: synthesis of 3-methylcyclohexenones
Author/Authors
Wang، نويسنده , , Fen and Liu، نويسنده , , Yuchen and Qi، نويسنده , , Zisong and Dai، نويسنده , , Wei and Li، نويسنده , , Xingwei، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2014
Pages
4
From page
6399
To page
6402
Abstract
A simple catalytic, redox-neutral access to 3-methylcyclohexenones has been developed via rhodium catalysis in the presence of an amine additive and Ag2CO3. This process utilized simple aldehydes and acetone as substrates and tolerates a variety of functional groups. Disubstituted phenols were isolated in moderate yields when Cu(OAc)2 was employed as an oxidant.
Keywords
Rhodium catalysis , Robinson annulation , phenol , 3-Methylcyclohexenones
Journal title
Tetrahedron Letters
Serial Year
2014
Journal title
Tetrahedron Letters
Record number
1891211
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